是的，AWS RDS Proxy可以直接与读取复制实例配对。以下是一个使用AWS SDK for Python（Boto3）创建RDS Proxy并与读取复制实例配对的示例代码：

import boto3

# 创建RDS Proxy
def create_rds_proxy(proxy_name, db_instance_arn, vpc_subnet_ids):
    client = boto3.client('rds')

    response = client.create_db_proxy(
        DBProxyName=proxy_name,
        EngineFamily='MYSQL',
        Auth={
            'AuthScheme': 'SECRETS',
            'Username': 'admin',
            'SecretArn': 'your_secret_arn'
        },
        RoleArn='your_role_arn',
        VpcSubnetIds=vpc_subnet_ids,
        DebugLogging=True
    )

    return response['DBProxy']['DBProxyArn']

# 将RDS Proxy与读取复制实例配对
def pair_proxy_with_instance(proxy_name, db_instance_arn):
    client = boto3.client('rds')

    response = client.modify_db_proxy(
        DBProxyName=proxy_name,
        DBInstances=[db_instance_arn]
    )

    return response['DBProxy']['DBProxyArn']

# 示例用法
proxy_name = 'my-rds-proxy'
db_instance_arn = 'your_db_instance_arn'
vpc_subnet_ids = ['subnet-12345678', 'subnet-87654321']

proxy_arn = create_rds_proxy(proxy_name, db_instance_arn, vpc_subnet_ids)
paired_proxy_arn = pair_proxy_with_instance(proxy_name, db_instance_arn)

print('RDS Proxy ARN:', proxy_arn)
print('Paired RDS Proxy ARN:', paired_proxy_arn)

请确保替换示例中的your_secret_arn、your_role_arn和your_db_instance_arn等参数为您实际使用的值。